W1M1 B Introduction to atomic orbital description |
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W1M1 C Common bonding pattern for C, N and O |
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W1M1 D Deconstruction of reactions |
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W1M1 E Arrow pushing |
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W1M2 A Geometric isomerism |
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W1M2 B CIP rule |
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W1M2 C Application of geometric isomerism |
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W1M2D1 cis trans Decalin |
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W1M2 D Geometric isomerism and healthy diet |
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W1M2 E hetero atom decalin |
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W1M3 A Basics of orbital |
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W1M3 Conformational analysis of alkanes, allylic strain |
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W1M3 D Dihedral angle analysis Klyne Prelog notation |
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W1M3 E Types of strain |
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W1M3 Introduction orbital, hybridisation, various projection |
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W1M3 Introduction to module 3 |
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W1M4 A Introduction to module 4 |
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W1M4 Conformations of cycloalkanes (3, 4 and 5 membered rings) |
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W1M4 Cyclohexane axial, equatorial bonds, ring flip |
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W1M4 Cyclohexane conformations, A-values |
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W1M4 Cyclohexane disubstituted, Prelog strain, fused rings |
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W1M4D6 Cyclopentane conformation |
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W1M4 E Conformational studies of Cyclopentane |
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W1M4 G A values in cyclohexyl derivatives |
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W1M4 I Comparison of various strains |
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W2M5 0 Symmetry and point group |
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W2M5 A Intro Module 5 |
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W2M5 B Reflection |
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W2M5 C Examples of Reflection inversion |
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W2M5D1 rotation |
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W2M5D2 reflection |
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W2M5D3 inversion |
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W2M5D4 improper rotation |
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W2M5 D Point Groups |
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W2M5 n Symmetry and point group |
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W2M5 Reflection, Inversion, Improper rotation |
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W2M6 A ethane |
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W2M6 B example C2H6 EtOH |
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W2M6 C sym chirality |
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W2M6D1 point group analysis |
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W2M6D2 C2H6 EtOH |
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W2M7 0 Stereochemical conventions D L, cis trans, R S, exo endo, erythro threo |
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W2M7 A stereo notation upto Fisher |
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W2M7 B stereo notation upto R S |
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W2M7 C stereo notation upto P M |
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W2M7D1 erythro threo |
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W2M7D2 fischer saw horse |
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W2M7D3 alpha beta |
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W2M7D4 cis trans |
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W2M7D5 exo endo part 1 |
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W2M7D10 RS Rotation of Bonds BN 1 |
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W2M7 n Stereochemical conventions D L, cis trans, R S, exo endo, erythro threo |
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W3M8 A Re Si topicity |
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W3M8 B enantiomer diastereomer comparison |
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W3M8 C topicity and chiral reagents |
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W3M8D1 Re Si attack hydride |
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W3M8D2 Re Si attack Bromide |
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W3M8D3 Re Si carbonyl |
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W3M8D4 enantiotopic faces |
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W3M8D5 diastereotopic faces |
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W3M8D6 meso |
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W3M8 n Re Si faces convention with examples and Topicity homotopic, enantiotopic 1 |
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W3M8 n Re Si faces convention with examples and Topicity homotopic, enantiotopic 2 |
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W3M9 A determination of absolute configuration |
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W3M9 B polarised light |
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W3M9 C ORD CD |
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W3M10 0 Optical rotatory dispersion and circular Dichroism its application, Axia |
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W3M10 A Cotton octant |
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W3M10 B ORD CD application |
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W3M10D1 Axial halo ketone |
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W3M10D2 octant intro 1 |
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W3M10D3 octant intro 2 |
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W3M10D4 octant example |
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W4M11 0 Stereochemical reactions, stereospecific reactions |
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W4M11 A Stereochemical Reactions |
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W4M11 B bromination |
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W4M11 C epoxidtion |
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W4M11D1 Anti Addition Bromide part 1 |
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W4M11D3 syn epoxidation |
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W4M11D4 Hydroboration Oxidation of Alkenes CIS Addition |
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W4M11 n Stereochemical reactions, stereospecific reactions |
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W4M12 0 Reactions involving stereo centres, Cram rule, Felkin Anh model, Prelog |
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W4M12 A reaction invovling stereo center |
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W4M12 B stereoselective reaction |
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W4M12D1 Reaction Involving Stereocenters |
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W4M12D2 Generation of 2nd chiral Centre |
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W4M12D3 Crams Rule Felkin Anh model |
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W5M12 n Reactions involving stereo centres, Cram rule, Felkin Anh model, Prelog |
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W5M13 0 Reactions of aromatic compounds_ Aromatic electrophilic substitution Nit |
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W5M13 A Aromatic Compounds |
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W5M13 B resonace stabilisation energy |
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W5M13 C Huckel Mo |
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W5M13D2 cyclobutadiene |
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W5M13D3 cyclopentadiene |
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W5M13D4 cycloheptatriene |
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W5M13 D ASE |
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W5M13 E Non Aromatic & Antiaromatic Compounds |
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W5M13 n Reactions of aromatic compounds_ Aromatic electrophilic substitution Nit |
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W5M14 0 Other Benzenoid derivatives_ Polycyclic aromatic hydrocarbon PAH, Clar r |
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W5M14 A Other Benzenoid Derivatives |
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W5M14-A Poly aromatic hydrocarbon 1 |
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W5M14 B Genesis of Clar Rule |
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W5M14 C Polyacenes |
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W5M14 D 6 Membered Aromatic Heterocycles |
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W5M14 E Annulenes |
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W5M14 n Other Benzenoid derivatives_ Polycyclic aromatic hydrocarbon PAH, Clar r |
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W6M15 0 Opening Reactions of aromatic compounds Aromatic electrophilic substitut |
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W6M15 n Closing Reactions of aromatic compounds Aromatic electrophilic substitut |
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W6M15V1 Aromatic Electrophilic substitution, sigma and pi complex |
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W6M15V2 Aromatic Electrophilic substitution, Nitration, Halogenation |
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W6M15V3 Aromatic Electrophilic Substitution-Friedel-Crafts reactions |
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W6M15V4 Aromatic Electrophilic Substitution Substituent effect_orientation |
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W6M16 0 Opening Substitution reactions of aromatic systems ╤В╨Р╨г 1 SNAr substitution |
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W6M16V1 Aromatic nucleophilic substitution-basics |
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W6M16V2 Aromatic nucleophilic substitution-Addition-Elimination |
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W6M16V3 Aromatic nucleophilic substitution-Elimination-Addition |
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W6M17 0 Opening Substitution reactions of aromatic systems ╤В╨Р╨г 2 Ipso substitution |
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W6M17 n Closing Substitution reactions of aromatic systems ╤В╨Р╨г 2 Ipso substitution |
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W6M17V1- SNAr-ipso attack |
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W6M17V2 Aromatic nucleophilic substitution-Reactions of ipso intermediate, Cine |
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W6M17V3 Aromatic nucleophilic substitution-von Richter reaction |
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W7M18 0 Opening Reaction dynamics Free energy profile, Hammond╤В╨Р╨йs Postulate |
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W7M18 n Closing Reaction dynamics Free energy profile, Hammond╤В╨Р╨йs Postulate |
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W7M18V1 Reaction dynamics-basics |
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W7M18V2 Reaction dynamics-Hammond's Postulate |
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W7M18V3 Hammond postulate application |
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W7M19 0 Opening Linear Free energy relationship, Part 1 Hammett equation |
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W7M19 n Closing Linear Free energy relationship, Part 1 Hammett equation |
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W7M19V1 LFER- Hammett equation |
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W7M19V2 Substituent constant |
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W7M19V3 reaction constant |
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W8M20 0 Opening Linear Free energy relationship, Part 2 Modification of Hammett |
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W8M20 n Closing Linear Free energy relationship, Part 2 Modification of Hammett |
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W8M20V1 Modification of Hammett equation |
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W8M20V2 Modification of Hammett equation |
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W8M20V3 Taft equation |
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W8M21 0 Opening Curtin Hammett principle, Winstein Holness equation |
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W8M21D1 Winstein-Holness eqn application |
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W8M21 n Closing Curtin Hammett principle, Winstein Holness equation |
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W8M21V1 Introduction, various R-S in organic chemistry |
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W8M21V2 Curtin- Hammett principle |
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W8M21V3 different cases of Curtin-Hammett principle |
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W8M22 0 Opening Carbocation, Part 1 Generation, Structure and Geometry of Carboc |
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W8M22 n Closing Carbocation, Part 1 Generation, Structure and Geometry of Carboc |
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W8M22V1 Carbocation Introduction, generation |
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W8M22V2 Structure, geometry, stability of carbocations |
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W8M22V3 carbocation stabilising groups |
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W9M23 0 Opening Carbocation, Part 2 Stabilisation of carbocation, Reactions |
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W9M23 n Closing Carbocation, Part 2 Stabilisation of carbocation, Reactions |
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W9M23V1 Carbocation stabilisation and reactions |
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W9M23V1 Stability of carbocation-old |
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W9M23V2 Carbocation-orbital interaction, NGP |
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W9M23V3 Reactions of carbocations |
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W9M23V4 Carbocation in biosynthesis |
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W9M24 0 Opening Carbocation, Rearrangement 1 No Change in carbon skeleton, Chang |
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W9M24D1 DEMO WAGNER MEERWIN REARRANGEMENT |
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W9M24 n Closing Carbocation, Rearrangement 1 No Change in carbon skeleton, Chang |
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W9M24V1 Carbocation rearrangement-1,2- hydride shift, Allyl rearrangement |
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W9M24V2 Carbocation rearrangement-Neopentyl, Wagner-Meerwin shift |
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W9M24V3 Carbocation rearrangement-Pinacol-Pinacolone Neopentyl, Wolff rearrangem |
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W9M25 0 Opening Carbocation, Rearrangement 2 involvement of other electron defic |
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W9M25 n Closing Carbocation, Rearrangement 2 involvement of other electron defic |
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W9M25V1 Carbocation rearrangement-Stereochemistry of rearrangement |
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W9M25V2 Carbocation rearrangement-migration to atoms other than carbon |
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W9M25V3 Carbocation rearrangement-Anchimeric assistance_NGP |
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W10M26 0 Opening Carbanions 1 pKa and its significance |
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W10M26 n Closing Carbanions 1 pKa and its significance |
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W10M26V1 pKa and its significance |
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W10M26V2 Parameters that affect pKa-1 |
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W10M26V3 Parameters that affect pKa-2 |
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W10M27 0 Opening Carbanions 2 Hard and Soft Acid and Base principle |
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W10M27 n Closing Carbanions 2 Hard and Soft Acid and Base principle |
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W10M27V1 Application of pKa |
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W10M27V2 HSAB principle |
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W10M27V3 Klopman Salem equation, FMO model |
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W10M27V4 Application of HSAB principle |
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W10M28 0 Opening Carbanions 3 Structure, Formation, Stability, Reactivity |
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W10M28 n Closing Carbanions 3 Structure, Formation, Stability, Reactivity |
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W10M28V1 Carbanion- Structure, formation |
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W10M28V2 Carbanion formation |
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W10M28V3 base vs nucleophile |
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W10M28V4 carbanion stability |
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W11M29V1 Carbanion Reactions- Benzoin condensation, Benzilic acid rearrangement |
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W11M29V2 Wittig, Stevens, Favorskii rearrangement |
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W11M29V3 Umpolung-polarity inversion, Henry reaction |
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W11M30V1 Free radical_ Structure and stability |
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W11M30V2 Fenton, Bouveault-Blanc reaction, Kolbe electrolysis, structure and ste |
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W11M30V3 Free radical stability, substituents effect |
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W12M31V1 Free radical - Stability and reactions |
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W12M31V2 Free radical - Stability-factors that are important |
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W12M31V3 Free radical - reactivity, radical philicity |
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W12M32V1 Free radical reactions- atom abstraction, bromination |
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W12M32V2 Free radical reactions - radical addition, disproportionation |
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W12M32V3 Free radical cyclisation |
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W13M33V1- Free radical reactions- Fenton reaction, Kolbe electrolysis, Bouveault |
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W13M33V2 - Giese reaction, Hofmann-Loffler reaction, Barton decarboxylation |
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W13M33V3-Barton-McCombie reaction, Birch reduction, Sandmeyer reaction, Radical |
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W13M34V1-Carbenes, Types and properties |
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W13M34V2 - Carbene-Generation, stability |
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W13M34V3 - Carbene- reactions, rearrangements, Nitrenes |
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W14M35V1-Carbonyl addition-1 |
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W14M35V2-Carbonyl addition 2 |
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W14M35V3-Carbonyl addition 3 |
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W14M36V1-Enols and enolate-1, haloform reaction, enolate formation |
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W14M36V2-Steric effect on enolate formation, regioselectivity, kinetic vs thermo |
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W14M36V3- Reactions of enolates, Alkylation of enolates, Michael addition |
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W14M37V1-Enamines, spectral evidences, formation of enamines |
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W14M37V2-Enamine formation, reactions of enamines |
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W14M37V3-Why enamines for alkylation, acylation of enamines |
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W15M38V1 Enol ethers, significance, formation of enol ethers |
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W15M38V2-Reactions of enol ethers, Mukaiyama Aldol reaction |
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W15M38V3 Choice of catalyst, Chemoselectivity, comparison of reactivity enolate |
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W15M39V1 Sharpless epoxidation, introduction, stereospecificity |
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W15M39V2-Sharpless epoxidation, stereospecificity, catalyst, catalytic cycle |
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W15M39V3 Click reaction, Cu Azide Alkyne Cycloaddition, mechanism of CuAAC |
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W15M40V1 Diels-Alder reaction, stereo and regioselectivity, rules governing DAR |
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W15M40V2 Examples of stereo and regio selectivity, exo-endo product |
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W15M40V3 FMO interactions, Intramolecular DAR, Heteroatom IMDA |
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